Hi, the sampling rate on the Xmegalab is 16MSPS, shared for both channels. The Xmegalab is currently not using the DMA for acquisition, although I think its possible.
To sample at 32MSPS I would suggest a faster microcontroller (like the AVR32 UC3), or even better. an FPGA + SRAM solution.
See my 
    oscilloscope comparison table
, look for open source designs and it will give you more ideas.